Dr. Evgeny Alekseev

Ludewig-Meyn-Str. 10, R 361 24118 Kiel Tel.: +49 431 880 2932 Fax: +49 431 880 4457 E-Mail: ea@min.uni-kiel.de, e_v_alekseev@mail.ru

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CV

• since 09.2005 (with breakes) Department of Crystallography, University of Kiel, Germany
• since 03.2004 Laboratory of X-ray analysis and Electron microscopy, Physical-Technical Research Institute, University of Nizhny Novgorod, Russia
• 2002-2004 PhD student, Department of Crystallography and Department of Solid State Chemistry, University of Nizhny Novgorod, Russia
• 1997 - 2002 student, Department of Solid Sate Chemistry, Faculty of Chemistry, University of Nizhny Novgorod, Russia

Research

• Structural chemistry of uranium compounds
• Thermodynamic properties of uranium compounds
• My research topic in Uni-Kiel is new aspects of structural chemistry of uranium compounds. We try to synthesize new uranium based compounds with interesting structural features such as cation-cationic interaction, high porosities, nano-fragments. Here showed some interesting results of our work:

Fig. 1. Fragment of crystal structure of Na2Li8[(UO2)11O12(WO5)2], first compound with three different uranium atoms coordination and strong cation-cation interaction. Angew. Chem. Int. Ed. 45-43. 7233-7235 (2006).	Fig. 2. Fragment of crystal structure of Li4[(UO2)10O10(Mo2O8)], in this phase realised new configuration of cation-cationic bonds - one-dimensional array. Inorg. Chem. 46. 21. 8442-8444 (2007)
Fig. 3. Fragment of crystal structure of (H3O)8[(H3O)@(18-crown-6)]2[(UO2)14(SO4)19(H2O)4](H2O)20.5, uranium compound with higher porosity known up this day. Angew. Chem. Int. Ed. 47. 549-551 (2008)	Fig. 4. Fragment of crystal structure of (H3O)2K[(H3O)@(18-crown-6)][(UO2)3(SeO4)5](H2O)4, interesting phase with nano-tubular fragments co-crystallized with crown ether molecules. Angew. Chem. Int. Ed. 47. 549-551 (2008)

Kooperation

• Prof. Dr. Thomas E. Albrecht-Schmitt, University of Notre Dame, U.S.A.
• Prof. Dr. Sergey Krivovichev, University of St. Petersburg, Russia
• Prof. Dr. Evgeny Suleimanov, University of Nizhny Novgorod, Russia

Publications

• Alekseev E.V., Krivovichev S.V., Depmeier W. Crystal chemistry of anhydrous Li uranyl phosphates and arsenates. II. Tubular fragments and cation-cation interactions in the 3D framework structures of Li6[(UO2)12(PO4)8(P4O13)], Li5[(UO2)13(AsO4)9(As2O7)], Li[(UO2)4(AsO4)3] and Li3[(UO2)7(AsO4)5O)]. J. Solid State Chem. (accepted, doi:10.1016/j.jssc.2009.08.003) (2009)
• Wu S., Ling J., Wang S., Skanthakumar S., Soderholm L., Albrecht-Schmitt T. E., Alekseev E. V. , Krivovichev S. V., Depmeier W. Uranium(VI) Adopts a Tetraoxo Core. Eur. J. Inorg. Chem. 29. 4039-4042(2009)
• Alekseev E.V., Krivovichev S.V., Depmeier W. Rubidium uranyl phosphates and arsenates with polymeric tetrahedral anions: syntheses and structures of Rb4[(UO2)6(P2O7)4(H2O)], Rb2[(UO2)3(P2O7)(P4O12)] and Rb[(UO2)2(As3O10)]. J. Solid State Chem. 182. 2074 - 2080 (2009)
• Alekseev E.V. , Krivovichev S.V., Depmeier W. Novel layered uranyl arsenates, Ag6[(UO2)2(As2O7)(As4O13)] and AI6[(UO2)2(AsO4)2(As2O7)] (AI- Ag and Na): first observation of a linear As4O136- anion and structure type evolution. J. Mater. Chem. 19. 2583 - 2587 (2009)
• Nagashima M., Rahmoun N.S.,Alekseev E.V., Geiger C., Armbruster T., Akasaka M. Crystal chemistry of macfallite: Relationships to sursassite and pumpellyite. American Mineralogist 93, 1851-1857 (2008)
• Alekseev E.V., Krivovichev S.V., Depmeier W. Crystal structure of [CH3NH3][(UO2)(H2AsO4)3]. Radiochemistry V50, 445-450 (2008)
• Alekseev E.V., Krivovichev S.V., Malcherek T., Depmeier W. Crystal chemistry of anhydrous Li uranyl phosphates and arsenates. I. a-Li[(UO2)(PO4)], a-Li[(UO2)(AsO4)], b-Li[(UO2)(AsO4)] and Li2[(UO2)3(P2O7)2]. J. Solid State Chem. 181, 3010-3015 (2008)
• Alekseev E.V., Krivovichev S.V., Depmeier W., K. Knorr. Complex topology of uranyl polyphosphate frameworks: crystal structures of a-,b-K[(UO2)(P3O9)] and K[(UO2)2(P3O10)]. Z. Anorg. Allgem. Chem. 634. 1527-1532 (2008)
• Alekseev E.V., Krivovichev S.V., Depmeier W. A Crown Ether as Template for Microporous and Nanostructured Uranium Compounds. Angewandte Chemie. 120, 559-561. Angewandte Chemie International Edition. 47. 549-551 (2008)
• Alekseev E.V., Krivovichev S.V., Malcherek T., Depmeier W. One-dimensional array of two- and three-center cation-cation bonds in the structure of Li4[(UO2)10O10(Mo2O8)]. Inorg. Chem. 46. 21. 8442-8444 (2007)
• Alekseev E.V., Krivovichev S.V., Armbruster T., Depmeier W., Suleimanov E.V., Chuprunov E.V., Golubev A.V. Dimensional reduction in alkali metal uranyl molybdates: Synthesis and structure of Cs-2[(UO2)O(MoO4)]. Z. Anorg. Allgem. Chem. 633. 1979-1984 (2007)
• Alekseev E.V., Krivovichev S.V., Depmeier W., Malcherek T., Suleimanov E.V., Chuprunov E.V. The crystal structure of Li4[(UO2)2(W2O10)] and crystal chemistry of Li uranyl tungstates. Zeitschrift fur Kristallographie. 222. 391-395 (2007)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Golubev A.V., Fukin G.K. Synthesis and crystal structure of Rb2U2MoO10. Russian Journal of Inorganic Chemistry. 52. 1446-1449 (2007)
• Suleimanov E.V., Chernorukov N.G., Golubev A.V., Medina E.A., Alekseev E.V. Physical chemistry of uranyl molibdates in system Rb2O-UO3-MoO3. Russian Journal of Inorganic Chemistry. 52. 1175-1179 (2007)
• Alekseev E.V., Krivovichev S.V., Depmeier W. K2[(UO2)As2O7] - the first uranium polyarsenate. Zeitschrift fur Anorganische und Allgemeine Chemie. 633. 1125-1126 (2007)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Fukin G.K., Baranov E.V. .Crystal structure of theUO(2)SO(4) center dot 2SO(CH3)(2) compound: A new type of uranyl sulfate ribbons and the UO2SO4 center dot 2SO (CH3)(2)-UO2SO4 center dot 2CO(NH2)(2) morphotropic transition. Crystallography Reports. 52. 266-270 (2007)
• Alekseev E.V., Krivovichev S.V., Depmeier W., Armbruster T., Katzke H., Suleimanov E.V., Chuprunov E.V. One-dimensional chains in uranyl tungstates: Syntheses and structures of A8[(UO2)4(WO4)4(WO5)2] (A = Rb, Cs) and Rb6[(UO2)2O(WO4)4]. Journal of solid state chemistry. 179. 2977-2987 (2006)
• Alekseev E.V., Krivovichev S.V., Depmeier W., Siidra O.I., Knorr K., Suleimanov E.V., Chuprunov E.V. Na2Li8[(UO2)11O12(WO5)2]: Three Different Types Uranyl-Ion Coordination Geometries and Cation-Cation Interactions. Angewandte Chemie. 118. 7391-7393. Angewandte Chemie International Edition 45-43. 7233-7235 (2006)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Fukin G.K. Crystal structure of uranyltungstate Cs2U2WO10. Journal of Structural Chemistry. 47. 895-899. (2006)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Marychev M.O., Ivanov V.A., Fukin G.K.Crystal structure and nonlinear optical properties of the K2UO2(SO4)(2) center dot 2H(2)O compound at 293K. Crystallography Reports. 51. 29-33 (2006)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Seregkin V.N., Fukin G.K. Crystal structures of Na0.98V0.98Mo1.02O6 and Na0.68V0.68Mo1.32O6 Russian Journal of Inorganic Chemistry. 50. 1369-1372 (2005)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Fukin G.K. Crystal structure of CoUO2(SO4)2*5H2O at 293K. Crystallography Reports. 50. 914-917. (2005)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Fukin G.K. Crystal structure of KAsUO6*4H2O at 100 and 293 K. Journal of Structural Chemistry. 46. 936-940 (2005)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Fukin G.K. Crystal structure of y-RbNbUO6*H2O. Radiochemistry. 47. 492-494. (2005)
• Alekseev E.V., Suleimanov E.V., Chuprunov E.V., Fukin G.K. Crystal structure of BaVUO6. Journal of Structural Chemistry. 45. 518-522. (2004)
• Alekseev E.V., Nosov S.S., Suleimanov E.V., Chernorukov N.G., Chuprunov E.V. Crystal structure of HAsUO6*4H2O. Journal of Structural Chemistry. 44. 506-510. (2003)
• Pushcharovskii D.Yu., Suleimanov E.V., Pasero M., Merlino S., Barinova A.V., Alekseev E.V. Crystal structure of Sr(AsUO6)2*8H2O. Crystallography Reports. 48. 212-215 (2003)
• Chernorukov N.G., Suleimanov E.V., Barch S.V., Alekseev E.V. Synthesis and study of lanthanide and yttrium uranophosphates. Radiochemistry. 43. 209-215 (2001)
• Chernorukov N.G., Suleimanov E.V., Barch S.V., Alekseev E.V. Synthesis and study of lanthanide and yttrium uranoarsenates. Radiochemistry. 43. 9-15. (2001)

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